Ascorbic acid sensor based on ZnO/B(PM-PA) nanocomposite
Keywords:
PMMA, PANI, ZnO, Ascorbic acid detection, ZnO/(PM-PA) nanocompositesAbstract
Recent years have seen a rise in interest in polymer nanocomposites based on electroactive conducting polymers with nanoparticle fillers because of their highly desirable multifunctional characteristics. A precise and considerate evaluation of AA is essential in the diagnosis of several mental disorders. Determining its presence in biological samples is still challenging since it coexists with other high-concentration biomolecules. We introduce a facile, eco-friendly Sensor B(PM-PA) Polymer blend (PB) and ZnO/B(PM-PA) nanocomposite (NCP). Analytical methods, including FT-IR, XRD analysis, and UV-Vis, were employed to explain these nanocomposites. A novel B(PM-PA)/ ZnO electrochemical biosensor was introduced for the in vivo detection of ascorbic acid. In addition, the electrocatalytic reduction of AA on PB&NCP was briefly investigated and achieved good analytical performance with an excellent linear range (0.03-0.1 µM), and a low detection limit (1.14mM&0.44µM). Therefore, the finding of PB&NCP nanocomposite can be regarded as an effective catalyst to enhance the AA detection
Downloads
References
S.Shrivastava, J.Nimisha, J.Rajeev,“Next-generation polymer nanocomposite-based electrochemical sensors and biosensors”,Trends in Analytical Chemistry82(2016):55-67.
A.S. Bhattacharyya, “Conducting polymers in biosensing: A review”, Chemical Physics Impact8(2024):100642-100651.
M.Yuqing, C. Jianrong, X. Xiaohuatitle, “Using electropolymerized non-conducting polymers to develop enzyme amperometric biosensors”, Trends Biotechnol22(2004): 227-231.
H. Meixner, U. Lampetitle, “Metal oxide sensors”,Sensors and Actuators B: Chemical 331(1996):198-202.
R. Soumyendu, S.Navneet, B.Reeti, D.S. Misra, A. James, M.C. Laughlin and S.R. Susanta, “Graphene oxide for electrochemical sensing applications”, Journal of Materials Chemistry21: (2011)14725-14731
L.Gaurav, H.M. Allan,F.Behzad Lin , L.Kasper, F. Kurtis, Q.Xian, M.G.Antonios, G. Balaji, “Two dimensional nanostructure-reinforced biodegradable polymeric nanocomposites for bone tissue engineering”, Biological macromolecules14(2013): 900–909.
M.M. Josuff Albar, N.A. Jamion, S.N. Atika Baharin, M. Raoov, K.P. Sambasevam, “ Preparation of novel commercial polyaniline composites for ammonia detection”,Solid-state phenomena301(2020):124–131.
H.Christian, H. Richard, S.S. Ulrich, “ PMMA based soluble polymeric temperature sensors based on UCST transition and solvatochromic dyes”, Polymer Chemistry1(2010): 1005–1008.
Z.Chao, G. Saravanan, G. Krishnan, H. YunSuk, Y. Kyusik, “AgNWs-PANI nanocomposite based electrochemical sensor for detection of 4-nitrophenol”, Sensors and Actuators B Chemical252(2017): 616-623.
W. Yansheng, G. Xiong, L. Yan, “Electrochemical sensors based on polyaniline nanocomposites for detecting Cd(II) in wastewater”, International Journal of Electrochemical Science19(2024):100519-100525.
S.P.Jong, H.J. Pum, M.P. Kwang, Y. Won-Chol, “Electrochemical Detection of Nitrite on PANI-TiO2/Pt Nanocomposite–Modified Carbon Paste Electrodes Using TOPSIS and Taguchi Methods”, ACS Omega 9 (2024): 30583–30593.
N.Shoaie, M. Daneshpour, M. Azimzadeh. S. Mahshid, S.M. Khoshfetrat, F. Jahanpeyma,A.Gholaminejad, K.Omidfar, M. Foruzandeh, “ Electrochemical sensors and biosensors based on the use of polyaniline and its nanocomposites: a review on recent advances”, Microchim Acta 186(2019): 465-472.
J. Yu, T.Huang, Z.Jiang, M. Sun, C. Tang, “ Synthesis and Characterizations of Zinc Oxide on Reduced Graphene Oxide for High-Performance Electrocatalytic Reduction of Oxygen”, Molecules 23(2018): 3227-3232
B. Salma, A. Ayesha,A.Haq Ali Shah, “ Highly Selective and Reproducible Electrochemical Sensing of Ascorbic Acid Through a Conductive Polymer Coated Electrode”,Polymers 11(2019): 1346-1351
J.A.Drisko, J. Chapman, V.J. Hunter, “The use of antioxidants with first-line chemotherapy in two cases of ovarian cancer”, Journal of the American College of Nutrition22(2003): 118–123.
G.Girma Salale, “ Recent advances in electrochemical sensors based on molecularly imprinted polymers and nanomaterials for detection of ascorbic acid, dopamine, and uric acid: A review”, Sensing and Bio-Sensing Research43(2024): 100610-100615.
W.U. Yiyong, D. Peihong, T. Yaling, F. Jinxia, X. Jingyun, L. Junhua, L. Jun, L. Guangli, H.W. Quanguo, “ Simultaneous and sensitive determination of ascorbic acid, dopamine, and uric acid via an electrochemical sensor based on PVP-graphene composite”,Journal of Nanobiotechnology18 (2020):11-15
S.H. Abu Hassan, M.M. Ramli, M. Abdullah, M.N. Mohtar, N.A. Rahman, A. Ahmad, N.H. Osman, F. Rusydi, “Effects of Polymerization Time towards Conductivity and Properties of Poly(methyl methacrylate)/ Polyaniline (PMMA/PANi) Copolymer”, Sustainability 14 (2022) :8940-8948
S.Angappane, N. Rajeev Kini, T.S. Natarajan, G. Rangarajan, B.Wessling, “ PAni–PMMA blend metal Schottky barriers” Thin Solid Films 417 (2002):202–205
M.M. Abutaliba, “Insights into the structural, optical, thermal, dielectric, and electrical properties of PMMA/PANI loaded with graphene oxide nanoparticles” Physica B Condensed Matter 552(2019):19–29
Z.H. Fatma, N. Nacira, “Improvement of the structural and electrical properties of PMMA/PANI MA blends synthesized by interfacial in situ polymerization in a continuous organic phase”, Polymer Bulletin 79 (2022): 37–63
Y.T.Mohamed, S. Adel, B. Cherifa, B. Ahmed, “Synthesis of Polyaniline-Zinc Oxide Composites: Assessment of Structural, Morphological, and Electrical Properties”, Annales de Chimie-Sciences des Materiaux 47 (2023): 399-404
J. Shanavas Khan, R. Asha, B. Beena, “ Polyaniline/Zinc Oxide Nanocomposite as a Remarkable Antimicrobial Agent in Contrast with PANI and ZnO”, Indian Journal of Adances in Chemical Science 6(2018) : 71-76.
S. Devikala, P. Kamaraj, M. Arthanareeswari, “Conductivity and Dielectric Studies of PMMA Composites”, Chemical Science Transactions 2(2013): S129-S134
B.Salma, A. Ayesha, A.S. Anwar-ul-Haq, “Highly Selective and Reproducible Electrochemical Sensing of Ascorbic Acid Through a Conductive Polymer Coated Electrode”, Polymers 11(2019): 1346-1352.
L.L.Israel, K. Sutripto, M.W. Lodrick, E.F. Olu, “ Polypyrrole@polyaniline-reduced graphene oxide nanocomposite support material and Cobalt for the enhanced electrocatalytic activity of nickel phosphide microsphere towards alkaline urea oxidation”, Materials Research Express 8(2021) :095303-095315
F. Zina, B.A.Mounir, N.A.Mohammed, D. Eithne, “Simultaneous determination of ascorbic acid, uric acid and dopamine using silver nanoparticles and copper monoamino-phthalocyanine functionalised acrylate polymer”, Analytical Methods 12(2020): 3883-3891
Downloads
Published
How to Cite
Issue
Section
License
This work is licensed under a Creative Commons Attribution 4.0 International License.
You are free to:
- Share — copy and redistribute the material in any medium or format
- Adapt — remix, transform, and build upon the material for any purpose, even commercially.
Terms:
- Attribution — You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
- No additional restrictions — You may not apply legal terms or technological measures that legally restrict others from doing anything the license permits.
