Investigating the Effects Of Sustainable Additives On The Performance And Microstructure Of Concrete
Keywords:
MCC, Fly Ash, Flexural Strength, X-ray diffractionAbstract
This research aims to explore the possibility of a dual binder system which is based on Fly Ash (FA) and Microcrystalline Cellulose Powder (MCC) as an alternative to Ordinary Portland Cement (OPC) concrete. The aim was to enhance both the mechanical and microstructural properties of concrete, and to increase sustainable construction practices. Concrete mixtures were designed to achieve a desired compressive strength of 30 MPa with w/c = 0.45. 10–25% of the cement was replaced by FA and 0.4–1.0% of MCC was added by the weight of the binder. The performance was evaluated in terms of the flexural strength, X-ray diffraction analysis (XRD), and bulk density. The blend with 15 wt% FA and 0.6 wt% MCC (M2) had best performance, with 5.5 MPa while 22.2% increase in flexural strength when compared to control mixture. Moreover, the density of M2 rose, implying denser microstructure. (2013) observed a decrease in the portlandite (Ca(OH)₂) peak intensity in mix M2, which suggested that a greater pozzolanic reaction was taking place. This reaction mechanism led to formation of additional C-S-H and enhanced both microstructure and strength. These findings demonstrate that FA with MCC-incorporated concrete can manufacture durable and sustainable concrete material containing high mechanical strengths. However the strengths and densities of specimens obtained by exceeding the optimal levels of FA and MCC, decreased, indicating the importance of dosage optimization. This study may provide an available route to develop green construction materials for sustainable infrastructure.
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Naik, T. R. (2008). Sustainability of Concrete Construction. Practice Periodical on Structural Design and Construction, 13(2), 98–103. https://doi.org/10.1061/(ASCE)1084-0680(2008)13:2(98)
Singh, M. (2024). Green Concrete: A step towards eco-friendly environment. World Journal of Advanced Engineering Technology and Sciences, 13(2), 549–554. https://doi.org/10.30574/wjaets.2024.13.2.0626
Findik, F. (2022). Green concrete for structural buildings. Heritage and Sustainable Development, 4(1), 67–76. https://doi.org/10.37868/hsd.v4i1.84
G. Habert, S.A. Miller, V.M. John, J.L. Provis, A. Favier, A. Horvath, K.L. Scrivener, Environmental impacts and decarbonization strategies in the cement and concrete industries, Nat Rev Earth Environ. 1 (2020) 559–573, https://doi.org/10.1038/ s43017-020-0093-3.
R. Bajpai, K. Choudhary, A. Srivastava, K.S. Sangwan, M. Singh, Environmental impact assessment of fly ash and silica fume based geopolymer concrete, J. Clean. Prod. 254 (2020), 120147, https://doi.org/10.1016/j.jclepro.2020.120147.
G. Habert, J.B. D’Espinose De Lacaillerie, N. Roussel, An environmental evaluation of geopolymer based concrete production: Reviewing current research trends, J. Clean. Prod. 19 (2011) 1229–1238, https://doi.org/10.1016/j. jclepro.2011.03.012.
M.E. Haque, Ndian Fly-Ash: Production and Consumption Scenario, Int J Waste Resour. 3 (2013) 22–25, https://doi.org/10.12777/ijwr.3.1.2013.22-25.
Indian Minerals Yearbook, Part- II Metals and Alloys 2018 (2020) 1–9.
H. Ye, A. Radli´ nska, Shrinkage mechanisms of alkali-activated slag, Cem. Concr. Res. 88 (2016) 126–135, https://doi.org/10.1016/j.cemconres.2016.07.001.
F. Collins, J.G. Sanjayan, Effect of pore size distribution on drying shrinking of alkali-activated slag concrete, Cem. Concr. Res. 30 (2000) 1401–1406, https://doi. org/10.1016/S0008-8846(00)00327-6. [8] Z. Li, M. Wyrzykowski, H. Dong, J. Granja, M. Azenha, P. Lura, G. Ye, Internal curing by superabsorbent polymers in alkali-activated slag, Cem. Concr. Res. 135 (2020), 106123, https://doi.org/10.1016/j.cemconres.2020.106123.
P. Chen, J. Wang, L. Wang, Y. Xu, Perforated cenospheres: A reactive internal curing agent for alkali activated slag mortars, Cem. Concr. Compos. 104 (2019), 103351, https://doi.org/10.1016/j.cemconcomp.2019.103351.
N.K. Lee, S.Y. Abate, H.-K. Kim, Use of recycled aggregates as internal curing agent for alkali-activated slag system, Constr. Build. Mater. 159 (2018) 286–296, https:// doi.org/10.1016/j.conbuildmat.2017.10.110.
Deng, Z. (2008). Flexural Fatigue Behavior of High Performance Cellulose Fiber and Hybrid Fibers Reinforced Concrete. https://en.cnki.com.cn/Article_en/CJFDTotal-GLGL200801040.htm
Bilcati, G. K., Maron da Costa, M. do R. de, da Silva, S. H. L., & Holzmann, H. A. (2024). An investigation on the impact of combined microfiber-microcrystalline cellulose addition on the performance of Portland cement composites. Revista IBRACON de Estruturas e Materiais, 18(1). https://doi.org/10.1590/s1983-41952025000800005
Zubair, N. (2017). Effects of Micro Cellulose Fibers Addition on Concrete Mechanical Properties Under Flexure and Uniaxial Tension. https://dspace.library.uvic.ca/handle/1828/8568
Bilcati, G. K., Maron da Costa, M. do R. de, da Silva, S. H. L., & Holzmann, H. A. (2024). An investigation on the impact of combined microfiber-microcrystalline cellulose addition on the performance of Portland cement composites. Revista IBRACON de Estruturas e Materiais, 18(1). https://doi.org/10.1590/s1983-41952025000800005
Chen, X., Chang, S., Jia, P., Yu, C., Wang, L., Zhao, J., & Tan, J. (n.d.). Reinforcing Concrete Slabs Using Cellulose Fiber. https://doi.org/10.13522/j.cnki.ggps.2021379
Nasir, M. S. R., Aziz, M. A., Zubair, M., Ashraf, N., Hussein, T. N., Allubli, M. K., Manzar, M. S., Al-Kutti, W. A., & Al-Harthi, M. A. (2022). Engineered cellulose nanocrystals-based cement mortar from office paper waste: Flow, strength, microstructure, and thermal properties. Journal of Building Engineering, 51, 104345. https://doi.org/10.1016/j.jobe.2022.104345
Maria S. Konsta-Gdoutos, Chrysoula A. Aza, Self sensing carbon nanotube (CNT) and nanofiber (CNF) cementitious composites for real time damage assessment in smart structures, Cem. Concr. Compos. 53 (2014) 162e169.
Serge Rebouillat, Fernand Pla, State of the art manufacturing and engineering of nanocellulose: a review of available data and industrial applications, J. Biomater. Nanobiotechnol. 4 (2) (2013) 165.
A., Dufresne, Nanocellulose: a new ageless bionanomaterial, Mater. Today 16 (6) 220e227.
Stephen J. Eichhorn, A. Dufresne, M. Aranguren, N.E. Marcovich, J.R. Capadona, S.J. Rowan, Christoph Weder, et al., Review: current international research into cellulose nanofibres and nanocomposites, J. Mater. Sci. 45 (1) (2010) 1e33.
Alper Kiziltas, Douglas J. Gardner, Yousoo Han, Han-Seung Yang, Mechanical properties of microcrystalline cellulose (MCC) filled engineering thermo plastic composites, J. Polym. Environ. 22 (3) (2014) 365e372.
Y. Cao, P. Zavaterri, J. Youngblood, R. Moon, J. Weiss, The influence of cellulose nanocrystal additions on the performance of cement paste, Cem. Concr. Compos. 56 (2015) 73e83.
Parveen, S., Rana, S., Fangueiro, R., & Paiva, M. C. (2017). A novel approach of developing micro crystalline cellulose reinforced cementitious composites with enhanced microstructure and mechanical performance. Cement and Concrete Composites, 78, 146–161. https://doi.org/10.1016/j.cemconcomp.2017.01.004
ASTM C618, Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use, Annual Book of ASTM Standards. (2022). 10.1520/C0618-22.
K. Vance, M. Aguayo, T. Oey, G. Sant, N. Neithalath, Hydration and strength development in ternary portland cement blends containing limestone and fly ash or metakaolin, Cem. Concr. Compos. 39 (2013) 93–103, https://doi.org/10.1016/j. cemconcomp.2013.03.028.
J.E. Oh, P.J.M. Monteiro, S.S. Jun, S. Choi, S.M. Clark, The evolution of strength and crystalline phases for alkali-activated ground blast furnace slag and fly ash- based geopolymers, Cem. Concr. Res. 40 (2010) 189–196, https://doi.org/ 10.1016/j.cemconres.2009.10.010.
S.D. Wang, K.L. Scrivener, Hydration products of alkali activated slag cement, Cem. Concr. Res. 25 (1995) 561–571, https://doi.org/10.1016/0008-8846(95)00045-E.
S. Zhang, Z. Li, B. Ghiassi, S. Yin, G. Ye, Fracture properties and microstructure formation of hardened alkali-activated slag/fly ash pastes, Cem. Concr. Res. 144 (2021), 106447, https://doi.org/10.1016/j.cemconres.2021.106447.
J.L. Costafreda, D.A. Martín, L. Presa, J.L. Parra, Effects of a natural mordenite as pozzolan material in the evolution of mortar settings, Mater 14 (18) (2021) 5343.
F. Kontoleontos, P. Tsakiridis, A. Marinos, N. Katsiotis, V. Kaloidas, M. Katsioti, Dry-grinded ultrafine cements hydration: physicochemical and microstructural characterization, Mater. Res. 16 (2013) 404–416.
Y. Sumra, S. Payam, I. Zainah, The pH of cement-based materials: a review, J. Wuhan Univ. Technol.-Materials Sci. Ed. 35 (2020) 908–924.
K.L. Scrivener, A. Nonat, Hydration of cementitious materials, present and future, Cement Concr. Res. 41 (7) (2011) 651–665.
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